Chapter 8. Capacitance
8.5 Molecular Model of a Dielectric
Learning Objectives
By the end of this section, you will be able to:
- Explain the polarization of a dielectric in a uniform electrical field
- Describe the effect of a polarized dielectric on the electrical field between capacitor plates
- Explain dielectric breakdown
We can understand the effect of a dielectric on capacitance by looking at its behavior at the molecular level. As we have seen in earlier chapters, in general, all molecules can be classified as either polar or nonpolar. There is a net separation of positive and negative charges in an isolated polar molecule, whereas there is no charge separation in an isolated nonpolar molecule (Figure 8.19). In other words, polar molecules have permanent electric-dipole moments and nonpolar molecules do not. For example, a molecule of water is polar, and a molecule of oxygen is nonpolar. Nonpolar molecules can become polar in the presence of an external electrical field, which is called induced polarization.

Let’s first consider a dielectric composed of polar molecules. In the absence of any external electrical field, the electric dipoles are oriented randomly, as illustrated in Figure 8.20(a). However, if the dielectric is placed in an external electrical field

The same effect is produced when the molecules of a dielectric are nonpolar. In this case, a nonpolar molecule acquires an induced electric-dipole moment because the external field
Therefore, when the region between the parallel plates of a charged capacitor, such as that shown in Figure 8.21(a), is filled with a dielectric, within the dielectric there is an electrical field
This net field can be considered to be the field produced by an effective charge

In most dielectrics, the net electrical field
Since
When the magnitude of an external electrical field becomes too large, the molecules of dielectric material start to become ionized. A molecule or an atom is ionized when one or more electrons are removed from it and become free electrons, no longer bound to the molecular or atomic structure. When this happens, the material can conduct, thereby allowing charge to move through the dielectric from one capacitor plate to the other. This phenomenon is called dielectric breakdown. (Figure 8.1 shows typical random-path patterns of electrical discharge during dielectric breakdown.) The critical value,
However, this limit becomes 60.0 kV when the same capacitor is filled with Teflon™, whose dielectric strength is about
which is about 42 times greater than a charge stored on an air-filled capacitor. Typical values of dielectric constants and dielectric strengths for various materials are given in Table 8.1. Notice that the dielectric constant
Material | Dielectric constant |
Dielectric strength |
---|---|---|
Vacuum | 1 | ∞ |
Dry air (1 atm) | 1.00059 | 3.0 |
Teflon™ | 2.1 | 60 to 173 |
Paraffin | 2.3 | 11 |
Silicon oil | 2.5 | 10 to 15 |
Polystyrene | 2.56 | 19.7 |
Nylon | 3.4 | 14 |
Paper | 3.7 | 16 |
Fused quartz | 3.78 | 8 |
Glass | 4 to 6 | 9.8 to 13.8 |
Concrete | 4.5 | – |
Bakelite | 4.9 | 24 |
Diamond | 5.5 | 2,000 |
Pyrex glass | 5.6 | 14 |
Mica | 6.0 | 118 |
Neoprene rubber | 6.7 | 15.7 to 26.7 |
Water | 80 | |
Sulfuric acid | 84 to 100 | |
Titanium dioxide | 86 to 173 | – |
Strontium titanate | 310 | 8 |
Barium titanate | 1,200 to 10,000 | – |
Calcium copper titanate | > 250,000 | – |
Not all substances listed in the table are good insulators, despite their high dielectric constants. Water, for example, consists of polar molecules and has a large dielectric constant of about 80. In a water molecule, electrons are more likely found around the oxygen nucleus than around the hydrogen nuclei. This makes the oxygen end of the molecule slightly negative and leaves the hydrogens end slightly positive, which makes the molecule easy to align along an external electrical field, and thus water has a large dielectric constant. However, the polar nature of water molecules also makes water a good solvent for many substances, which produces undesirable effects, because any concentration of free ions in water conducts electricity.
Example
Electrical Field and Induced Surface Charge
Suppose that the distance between the plates of the capacitor in Example 8.10 is 2.0 mm and the area of each plate is
Strategy
In part (a), we know that the voltage across the empty capacitor is
Solution
Show Answer
- The electrical field
between the plates of an empty capacitor is
The electrical field E with the Teflon™ in place is
- The effective charge on the capacitor is the difference between the free charge
and the induced charge . The electrical field in the Teflon™ is caused by this effective charge. Thus
We invert this equation to obtain , which yields
Example
Inserting a Dielectric into a Capacitor Connected to a Battery
When a battery of voltage

Strategy
We identify the known values:
Solution
Show Answer
(a) The capacitance of the filled capacitor is
(b) For the filled capacitor, the free charge on the plates is
The electrical field E in the filled capacitor is due to the effective charge
Solving this equation for
Significance
Notice that for materials with dielectric constants larger than 2 (see Table 8.1), the induced charge on the surface of dielectric is larger than the charge on the plates of a vacuum capacitor. The opposite is true for gasses like air whose dielectric constant is smaller than 2.
Check Your Understanding
Continuing with Example 8.12, show that when the battery is connected across the plates the energy stored in dielectric-filled capacitor is
Check Your Understanding
Repeat the calculations of Example 8.10 for the case in which the battery remains connected while the dielectric is placed in the capacitor.
Show Solution
a.
Summary
- When a dielectric is inserted between the plates of a capacitor, equal and opposite surface charge is induced on the two faces of the dielectric. The induced surface charge produces an induced electrical field that opposes the field of the free charge on the capacitor plates.
- The dielectric constant of a material is the ratio of the electrical field in vacuum to the net electrical field in the material. A capacitor filled with dielectric has a larger capacitance than an empty capacitor.
- The dielectric strength of an insulator represents a critical value of electrical field at which the molecules in an insulating material start to become ionized. When this happens, the material can conduct and dielectric breakdown is observed.
Key Equations
Capacitance | |
Capacitance of a parallel-plate capacitor | |
Capacitance of a vacuum spherical capacitor | |
Capacitance of a vacuum cylindrical capacitor | |
Capacitance of a series combination | |
Capacitance of a parallel combination | |
Energy density | |
Energy stored in a capacitor | |
Capacitance of a capacitor with dielectric | |
Energy stored in an isolated capacitor with dielectric |
|
Dielectric constant | |
Induced electrical field in a dielectric |
Conceptual Questions
Distinguish between dielectric strength and dielectric constant.
Show Solution
Dielectric strength is a critical value of an electrical field above which an insulator starts to conduct; a dielectric constant is the ratio of the electrical field in vacuum to the net electrical field in a material.
Water is a good solvent because it has a high dielectric constant. Explain.
Water has a high dielectric constant. Explain why it is then not used as a dielectric material in capacitors.
Show Solution
Water is a good solvent.
Elaborate on why molecules in a dielectric material experience net forces on them in a non-uniform electrical field but not in a uniform field.
Explain why the dielectric constant of a substance containing permanent molecular electric dipoles decreases with increasing temperature.
Show Solution
When energy of thermal motion is large (high temperature), an electrical field must be large too in order to keep electric dipoles aligned with it.
Give a reason why a dielectric material increases capacitance compared with what it would be with air between the plates of a capacitor. How does a dielectric material also allow a greater voltage to be applied to a capacitor? (The dielectric thus increases C and permits a greater V.)
Elaborate on the way in which the polar character of water molecules helps to explain water’s relatively large dielectric constant.
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answers may vary
Sparks will occur between the plates of an air-filled capacitor at a lower voltage when the air is humid than when it is dry. Discuss why, considering the polar character of water molecules.
Problems
Two flat plates containing equal and opposite charges are separated by material 4.0 mm thick with a dielectric constant of 5.0. If the electrical field in the dielectric is 1.5 MV/m, what are (a) the charge density on the capacitor plates, and (b) the induced charge density on the surfaces of the dielectric?
For a Teflon™-filled, parallel-plate capacitor, the area of the plate is
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a. 37 nC; b. 0.4 MV/m; c. 19 nC
Find the capacitance of a parallel-plate capacitor having plates with a surface area of
(a) What is the capacitance of a parallel-plate capacitor with plates of area
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a.
Two parallel plates have equal and opposite charges. When the space between the plates is evacuated, the electrical field is
The dielectric to be used in a parallel-plate capacitor has a dielectric constant of 3.60 and a dielectric strength of
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When a 360-nF air capacitor is connected to a power supply, the energy stored in the capacitor is
A parallel-plate capacitor has square plates that are 8.00 cm on each side and 3.80 mm apart. The space between the plates is completely filled with two square slabs of dielectric, each 8.00 cm on a side and 1.90 mm thick. One slab is Pyrex glass and the other slab is polystyrene. If the potential difference between the plates is 86.0 V, find how much electrical energy can be stored in this capacitor.
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Additional Problems
A capacitor is made from two flat parallel plates placed 0.40 mm apart. When a charge of
An air-filled (empty) parallel-plate capacitor is made from two square plates that are 25 cm on each side and 1.0 mm apart. The capacitor is connected to a 50-V battery and fully charged. It is then disconnected from the battery and its plates are pulled apart to a separation of 2.00 mm. (a) What is the capacitance of this new capacitor? (b) What is the charge on each plate? (c) What is the electrical field between the plates?
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a. 0.277 nF; b. 27.7 nC; c. 50 kV/m
Suppose that the capacitance of a variable capacitor can be manually changed from 100 to 800 pF by turning a dial connected to one set of plates by a shaft, from
Earth can be considered as a spherical capacitor with two plates, where the negative plate is the surface of Earth and the positive plate is the bottom of the ionosphere, which is located at an altitude of approximately 70 km. The potential difference between Earth’s surface and the ionosphere is about 350,000 V. (a) Calculate the capacitance of this system. (b) Find the total charge on this capacitor. (c) Find the energy stored in this system.
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a. 0.065 F; b. 23,000 C; c. 4.0 GJ
A
Three capacitors having capacitances of 8.40, 8.40, and 4.20
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a.
A parallel-plate capacitor with capacitance
(a) How much energy is stored in the electrical fields in the capacitors (in total) shown below? (b) Is this energy equal to the work done by the 400-V source in charging the capacitors?

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a. 0.13 J; b. no, because of resistive heating in connecting wires that is always present, but the circuit schematic does not indicate resistors
Three capacitors having capacitances 8.4, 8.4, and 4.2
(a) An
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a.
(a) On a particular day, it takes
(a) A certain parallel-plate capacitor has plates of area
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a. 14.2 kV; b. The voltage is unreasonably large, more than 100 times the breakdown voltage of nylon. c. The assumed charge is unreasonably large and cannot be stored in a capacitor of these dimensions.
A prankster applies 450 V to an
Challenge Problems
A spherical capacitor is formed from two concentric spherical conducting spheres separated by vacuum. The inner sphere has radius 12.5 cm and the outer sphere has radius 14.8 cm. A potential difference of 120 V is applied to the capacitor. (a) What is the capacitance of the capacitor? (b) What is the magnitude of the electrical field at
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a. 89.6 pF; b. 6.09 kV/m; c. 4.47 kV/m; d. no
The network of capacitors shown below are all uncharged when a 300-V potential is applied between points A and B with the switch S open. (a) What is the potential difference
Electronic flash units for cameras contain a capacitor for storing the energy used to produce the flash. In one such unit the flash lasts for 1/675 fraction of a second with an average light power output of 270 kW. (a) If the conversion of electrical energy to light is 95% efficient (because the rest of the energy goes to thermal energy), how much energy must be stored in the capacitor for one flash? (b) The capacitor has a potential difference between its plates of 125 V when the stored energy equals the value stored in part (a). What is the capacitance?
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a. 421 J; b. 53.9 mF
A spherical capacitor is formed from two concentric spherical conducting shells separated by a vacuum. The inner sphere has radius 12.5 cm and the outer sphere has radius 14.8 cm. A potential difference of 120 V is applied to the capacitor. (a) What is the energy density at
A metal plate of thickness t is held in place between two capacitor plates by plastic pegs, as shown below. The effect of the pegs on the capacitance is negligible. The area of each capacitor plate and the area of the top and bottom surfaces of the inserted plate are all A. What is the capacitance of this system?
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A parallel-plate capacitor is filled with two dielectrics, as shown below. When the plate area is A and separation between plates is d, show that the capacitance is given by
A parallel-plate capacitor is filled with two dielectrics, as shown below. Show that the capacitance is given by
Show Solution
proof
A capacitor has parallel plates of area
Glossary
- dielectric breakdown
- phenomenon that occurs when an insulator becomes a conductor in a strong electrical field
- dielectric strength
- critical electrical field strength above which molecules in insulator begin to break down and the insulator starts to conduct
- induced electric-dipole moment
- dipole moment that a nonpolar molecule may acquire when it is placed in an electrical field
- induced electrical field
- electrical field in the dielectric due to the presence of induced charges
- induced surface charges
- charges that occur on a dielectric surface due to its polarization
Licenses and Attributions
Molecular Model of a Dielectric. Authored by: OpenStax College. Located at: https://openstax.org/books/university-physics-volume-2/pages/8-5-molecular-model-of-a-dielectric. License: CC BY: Attribution. License Terms: Download for free at https://openstax.org/books/university-physics-volume-2/pages/1-introduction